理学部化学科

メニュー

加知千裕／教授

氏名

加知千裕（Chihiro Kachi）

研究室のページ

経歴

岐阜大学大学院工学研究科応用化学専攻博士前期課程修了
社団法人未踏科学技術協会勤務
東京都立大学大学院理学研究科化学専攻博士後期課程修了. 博士号（理学）取得
横浜市立大学大学院国際総合科学研究科博士研究員を経て、東邦大学理学部化学科講師
東邦大学理学部化学科准教授
トロント大学（Andrew Woolley Lab）客員研究員 (2015-2016)
東邦大学理学部化学科教授

専門分野

錯体化学

主な研究課題

可逆的共有結合を用いた金属錯体の物性制御
光機能性金属錯体の合成と物性開拓

主な研究業績

＜論文＞

Nobuo Yasuike, Chihiro Kachi-Terajima, Amir Karin, Takashi Mino, and G.Andrew Woolley (2022):
Modification of proteins with azobenzene crosslinkers using reversible covalent bonds, Org. Biomol. Chem., 2022, 20, 8649–8656.
Chihiro Kachi-Terajima, Yuto Inaba, and Kaito Tsuruga (2022):
Synthesis, crystal structure and determination of the pKa value of 2,6-dimethoxycyclohexa-2,5-diene-1,4-dione 1-[2-(quinolin-8-yl)hydrazone], Acta Cryst., 2022, C78, 371–375.
Chihiro Kachi-Terajima and Seiya Hagiwara (2022):
Synthesis, crystal structure and photophysical properties of chlorido [(E)-3-hydroxy-2-methyl-6-(quinolin-8-yldiazenyl)phenolato]copper(II) monohydrate, Acta Cryst., 2022, E78, 473–476.
Chihiro Kachi-Terajima, Miku Okubo, Mari Ikeda, and Yoichi Habata (2021):
Luminescence switch based on the acid/base induced reversibility of covalent bonds in lanthanide(III) complexes, Chem. Commun., 2021, 57, 10939-10942.
Chihiro Kachi-Terajima, Naoya Mutoh, Yuta Sasada, and Kaori Anjo (2020):
Cyclometalation reactions of platinum complexes with azo-and imine-based ligands: Ligand-dependent and water-induced C-H activation, J. Organomet. Chem., 2020, 928, 121548. Special issue of JOM for "stimuli-responsive organometallic complexes".
Chihiro Kachi-Terajima, Tasuku Eiba, Rikako Ishii, Hitoshi Miyasaka, Yuta Kodama, and Toshiaki Saito (2020):
Spin Ice-like Magnetic Relaxation of a Two-dimensional Network based on Manganese(III) Salen-type Single-Molecule Magnets, Angew. Chem. Int. Ed., 2020, 59, 22048-22053, Hot Paper, Frontispiece.
Chihiro Kachi-Terajima, Norihisa Kimura, Yuka Tomori, Daiisuke Akahoshi, Toshiaki Saito (2018):
Solvent-dependent structures of lanthanide-TCNQ coordination networks and their magnetic properties, J. Coord. Chem., 2018, 71, 3600-3614.
Chihiro Kachi-Terajima, and Norihisa Kimura（2018):
Crystal structures of two isotypic lanthanide(III) complexes: triaqua[2,6-diacetylpyridine bis(benzoylhydrazone)]methanollanthanide (III) trichloride methanol disolvates (Ln^III = Tb and Dy), Acta Cryst., 2018, E74, 535–538.
Chihiro Kachi-Terajima, Takeru Shimoyama, Takahiro Ishigami, Mari Ikeda and Yoichi Habata (2018):
A hemiaminal–ether structure stabilized by lanthanide complexes with an imidazole-based Schiff base ligand, Dalton Trans., 2018, 47, 2638–2645.
Chihiro Kachi-Terajima, Rikako Ishii, Yoshiaki Tojo, Masato Fukuda, Yasutaka Kitagawa, Mizuki Asaoka, and Hitoshi Miyasaka (2017):
Ferromagnetic Exchange Coupling in a Family of Mn^III Salen-Type Schiff-Base Out-of-Plane Dimers, J. Phys. Chem. C., 2017, 121, 12454−12468.
Mari Ikeda, Ajay Kumar Sah, Miki Iwase, Rina Murashige, Jun-ichi Ishi-i, Masatoshi Hasegawa,Chihiro Kachi-Terajima (2017):
C–H⋯Cl⁻hydrogen bonds in solution and in the solid-state: HgCl₂complexes with cyclen-based cryptands, Dalton Trans., 2017, 46, 3800–3804.
Chihiro Kachi-Terajima, Megumi Ishii, Toshiaki Saito, Chikahide Kanadani, Takunori Harada, and Reiko Kuroda (2012):
Homochiral 1D Helical Chain Based on an Achiral Cu(II) Complex, Inorg. Chem., 2012, 51, 7502–7507.
Tomoyuki Mochida, Yusuke Funasako, Takanori Kishida,Chihiro Kachi-Terajima (2012):
Assembled Structures and Magnetic Properties of Viologen–[M(mnt) ₂] Charge-transfer Salts (mnt = maleonitriledithiolato; M = Cu, Ni, Pt), Inorg. Chim. Acta., 2012, 384, 111–116.
Akiko Hori, Takahiro Kikuchi, Kumiko Miyamoto, Takashi Okano, Chihiro Kachi-Terajima, Hiroshi Sakaguchi (2011):
Transformation of a Cu^II Thiazolo-1,2,4-triazine Derivative from a MetastableCoordination Network to a Monomer in Solution and Vapor Conditions, Eur. J. Inorg. Chem., 2011, 20, 3059–3066.
Chihiro Kachi-Terajima, Katsuya Yanagi, Toru Kaziki, Takafumi Kitazawa, Miki Hasegawa (2011):
Luminescence tuning of imidazole-based lanthanide(III) complexes [Ln = Sm, Eu, Gd, Tb, Dy], Dalton Trans., 2011, 40, 2249–2256. (Themed issue on New Talent: Asia).
Chihiro Kachi-Terajima, Erina Mori, Tasuku Eiba, Toshiaki Saito, Chikahide Kanadani, Takafumi Kitazawa,Hitoshi Miyasaka (2010):
Mn^IIISalen-type Single-molecule Magnet Fixed in a Two-dimensional Network, Chem. Lett., 2010, 39, 94–95.