理学部化学科

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加知千裕/准教授

氏名

加知千裕(Chihiro Kachi)
加知千裕/准教授

経歴

  • 岐阜大学工学部応用化学科卒業
  • 岐阜大学大学院工学研究科応用化学専攻博士前期課程修了
  • 社団法人未踏科学技術協会勤務
  • 東京都立大学大学院理学研究科化学専攻博士後期課程修了. 博士号(理学)取得
  • 横浜市立大学大学院国際総合科学研究科博士研究員を経て、東邦大学理学部化学科講師
  • 東邦大学理学部化学科准教授

専門分野

錯体化学

主な研究課題

      
  • 可逆的共有結合を用いた金属錯体の物性制御
  • 光機能性金属錯体の合成と物性開拓

主な研究業績

<論文>
  • Chihiro Kachi-Terajima, Naoya Mutoh, Yuta Sasada, and Kaori Anjo (2020):
    Cyclometalation reactions of platinum complexes with azo-and imine-based ligands: Ligand-dependent and water-induced C-H activation, J. Organomet. Chem., 2020, 928, 121548. Special issue of JOM for "stimuli-responsive organometallic complexes".
  • Chihiro Kachi-Terajima, Tasuku Eiba, Rikako Ishii, Hitoshi Miyasaka, Yuta Kodama, and Toshiaki Saito (2020):
    Spin Ice-like Magnetic Relaxation of a Two-dimensional Network based on Manganese(III) Salen-type Single-Molecule Magnets, Angew. Chem. Int. Ed., 2020, 59, 22048-22053, Hot Paper, Frontispiece.
  • Chihiro Kachi-Terajima, Norihisa Kimura, Yuka Tomori, Daiisuke Akahoshi, Toshiaki Saito (2018):
    Solvent-dependent structures of lanthanide-TCNQ coordination networks and their magnetic properties, J. Coord. Chem., 2018, 71, 3600-3614.
  • Chihiro Kachi-Terajima, and Norihisa Kimura(2018):
    Crystal structures of two isotypic lanthanide(III) complexes: triaqua[2,6-diacetylpyridine bis(benzoylhydrazone)]methanollanthanide (III) trichloride methanol disolvates (LnIII = Tb and Dy), Acta Cryst., 2018, E74, 535–538.
  • Chihiro Kachi-Terajima, Takeru Shimoyama, Takahiro Ishigami, Mari Ikeda and Yoichi Habata (2018):
    A hemiaminal–ether structure stabilized by lanthanide complexes with an imidazole-based Schiff base ligand, Dalton Trans., 2018, 47, 2638–2645.
  • Chihiro Kachi-Terajima, Rikako Ishii, Yoshiaki Tojo, Masato Fukuda, Yasutaka Kitagawa, Mizuki Asaoka, and Hitoshi Miyasaka (2017):
    Ferromagnetic Exchange Coupling in a Family of MnIII Salen-Type Schiff-Base Out-of-Plane Dimers, J. Phys. Chem. C., 2017, 121, 12454−12468.
  • Mari Ikeda, Ajay Kumar Sah, Miki Iwase, Rina Murashige, Jun-ichi Ishi-i, Masatoshi Hasegawa,Chihiro Kachi-Terajima (2017):
    C–H⋯Clhydrogen bonds in solution and in the solid-state: HgCl2complexes with cyclen-based cryptands, Dalton Trans., 2017, 46, 3800–3804.
  • Chihiro Kachi-Terajima, Megumi Ishii, Toshiaki Saito, Chikahide Kanadani, Takunori Harada, and Reiko Kuroda (2012):
    Homochiral 1D Helical Chain Based on an Achiral Cu(II) Complex, Inorg. Chem., 2012, 51, 7502–7507.
  • Tomoyuki Mochida, Yusuke Funasako, Takanori Kishida,Chihiro Kachi-Terajima (2012):
    Assembled Structures and Magnetic Properties of Viologen–[M(mnt) 2] Charge-transfer Salts (mnt = maleonitriledithiolato; M = Cu, Ni, Pt), Inorg. Chim. Acta., 2012, 384, 111–116.
  • Akiko Hori, Takahiro Kikuchi, Kumiko Miyamoto, Takashi Okano, Chihiro Kachi-Terajima, Hiroshi Sakaguchi (2011):
    Transformation of a CuII Thiazolo-1,2,4-triazine Derivative from a MetastableCoordination Network to a Monomer in Solution and Vapor Conditions, Eur. J. Inorg. Chem., 2011, 20, 3059–3066.
  • Chihiro Kachi-Terajima, Katsuya Yanagi, Toru Kaziki, Takafumi Kitazawa, Miki Hasegawa (2011):
    Luminescence tuning of imidazole-based lanthanide(III) complexes [Ln = Sm, Eu, Gd, Tb, Dy], Dalton Trans., 2011, 40, 2249–2256. (Themed issue on New Talent: Asia).
  • Chihiro Kachi-Terajima,Erina Mori, Tasuku Eiba, Toshiaki Saito, Chikahide Kanadani, Takafumi Kitazawa,Hitoshi Miyasaka (2010):
    MnIIISalen-type Single-molecule Magnet Fixed in a Two-dimensional Network, Chem. Lett., 2010, 39, 94–95.
  • C. Kachi-Terajima, H. Miyasaka, A. Saitoh, N. Shirakawa, M. Yamashita, R. Clérac (2007):
    Single-Molecule Magnet Behavior in Heterometallic MII-MnIII2-MII Tetramers (MII = Cu, Ni)Containing MnIII Salen-Type Dinuclear Core, Inorg. Chem., 46, 5861-5872.
  • S. Takamizawa, C. Kachi-Terajima,  M. Kohbara, T. Akatsuka, T. Jin (2007):
    Alcohol-Vapor Inclusion in Single-Crystal Adsorbents [M2(bza)4(pyz)]n (M=Rh, Cu): Structural Study and Application to Separation Membranes, Chem. Asian. J., 2, 837-848.
  • C. Kachi-Terajima, T. Akatsuka, M. Kohbara, S. Takamizawa (2007):
    Structural and Magnetic Study of N2, NO, NO2, and SO2Adsorbed within a Flexible Single-Crystal Adsorbent of  [Rh2(bza)4(pyz)]n,  Chem. Asian.J., 2, 40-50.
  • T. Ueda, K. Kurokawa, T. Eguchi, C. Kachi-Terajima, S. Takamizawa (2007):
    Local Structure and Xenon Adsorption Behavior of Metal-Organic Framework System [M2(O2CPh)4(pyz)]n (M = Rh and Cu) As Studied with Use of Single-Crystal X-ray Diffraction, Adsorption Isotherm, and Xenon-129 NMR, J. Phys. Chem. C, 111, 1524-1534.
  • C. Kachi-Terajima, T. Akatsuka, M. Kohbara, S. Takamizawa (2007):
    Magnetic Properties of Nitric Oxide Adsorbed within Channel Crystals, Polyhedron, 26, 1876-1880.

主な担当科目

錯体化学
無機・分析化学演習I
無機・分析化学演習II
無機・分析化学実験
無機・分析化学I (大学院)

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